Acids and bases: Their quantitative behaviour

Ccxvi. Physical Chemistry of Lipoids. v. Behaviour of Kephalin from Human Brain towards Acids and Bases

On the behaviour of biradicaloid [P(μ-NTer)]2 towards Lewis acids and bases.

The well-known diphosphadiazane-1,3-diyl [P(μ-NTer)]2 (Ter = 2,6-bis(2,4,6-trimethyl-phenyl)-phenyl) was treated with Lewis bases such as N-heterocyclic carbenes and Lewis acids e.g. gold(i) chloride complexes. In the reaction with the Lewis base, fragmentation of the P2N2 framework was observed, yielding a salt of the type [(NHC)2P](+)[(TerN)2P](-) in a clean reaction. The reaction of [P(μ-NTe...

Asymptotic Behaviour of Standard Bases

We prove that the elements of any standard basis of In, where I is an ideal of a Noetherian local ring and n is a positive integer, have order bounded by a linear function in n. We deduce from this that the elements of any standard basis of In in the sense of Grauert-Hironaka, where I is an ideal of the ring of power series, have order bounded by a polynomial function in n. The aim of this pape...

The Theory of Acids and Bases

The Water or Arrhenius Theory was widely accepted up to the early years of this century . It defines an acid as a hydrogen compound ionizing in water to give hydrogen ions, and a base as a hy<iToxyl compound which gives hydroxide ions in water. The neutralization reaction between an acid and a base produces a salt and water only: HA(ac id) + BOH(base) ""' BA(salt) + H 20(water) and the salts so...

Precise Coulometric Titration of Acids and Bases

Apparatus and techniques a re dc~cribed for t he t itration of ac ids a nd. bases by constantcurrent coulometry. The precision nnd accuraey of t he method aI~e JndLcated by tl traLlons of benzoic acid, potass ium acid pMhalate, adLpiC aCld, hydroc~lo l'l c aCid, ~nd sod ium eal'bonate. Standard deviations of ± 0.003 p er cent have been obtaIned which LndlCatp. that the reliabi li ty of the meth...